COLLAGEN-CONTAINING NITROGEN–BORON FIRE-RETARDANT COMPOSITION FOR NATURAL LEATHER

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Xakimova M.Sh. Islamova D.A.. Rafiqov A.S. Kadirov Sh.U.

Abstract

Most substances used for the final finishing of natural leather significantly increase its flammability. However, for the use of leather materials in the automotive, furniture, and light industries, it is important to impart flame-retardant properties to them. Due to the toxicity of traditional halogen-containing flame retardants, particular interest is given to the use of halogen-free nitrogen-, boron-, and phosphorus-containing fire-retardant compositions. To address this issue, a composition based on collagen and polyacrylamide, characterized by a high nitrogen content, with the addition of boron-containing compounds, was used in this study. Samples of finished natural leather and suede splits were treated with this composition. The fire-retardant and morphological properties of the samples were investigated. The obtained results showed a reduction in the flame propagation rate of materials treated with the nitrogen–boron-containing composition. Surface structure analysis confirmed the formation of a film coating.

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COLLAGEN-CONTAINING NITROGEN–BORON FIRE-RETARDANT COMPOSITION FOR NATURAL LEATHER. (2025). Journal of Multidisciplinary Sciences and Innovations, 4(10), 1390-1396. https://doi.org/10.55640/

References

1. Wang, L., Lyu, B., Gao, D., Ren, J., Wang, Y., & Ma, J. (2025). Organic-inorganic hybrid leather fatliquoring agent with fluidity: Enhanced flame retardancy and physical-mechanical properties for leather collagen fibers. International Journal of Biological Macromolecules, 308, 142380. https://doi.org/10.1016/j.ijbiomac.2025.142380

2. Sundar, V. J., Gnanamani, A., Muralidharan, C., Chandrababu, N. K., & Mandal, A. B. (2011). Recovery and utilization of proteinous wastes of leather making: A review. Reviews in Environmental Science and Biotechnology, 10(2), 151–163. https://doi.org/10.1007/s11157-010-9223-6

3. Maliha, M., Rashid, T. U., & Rahman, M. M. (2024). A green strategy for collagen extraction from tannery raw trimmings using papain enzyme: Process optimization by MW-TOPSIS for enhanced yield. International journal of biological macromolecules, 262(Pt 2), 130040. https://doi.org/10.1016/j.ijbiomac.2024.130040

4. Maistrenko, L., Iungin, O., Pikus, P., Pokholenko, I., Gorbatiuk, O., Moshynets, O., Okhmat, O., Kolesnyk, T., Potters, G., & Mokrousova, O. (2022). Collagen Obtained from Leather Production Waste Provides Suitable Gels for Biomedical Applications. Polymers, 14(21), 4749. https://doi.org/10.3390/polym14214749

5. Rafikov, A. S., Khakimova, M. S., Fayzullayeva, D. A., & Reyimov, A. F. (2020). Microstructure, morphology and strength of cotton yarns sized by collagen solution. Cellulose, 27, 10369–10384. https://doi.org/10.1007/s10570-020-03450-w

6. Masilamani, D., Madhan, B., Shanmugam, G., Palanivel, S., & Narayan, B. (2016). Extraction of collagen from raw trimming wastes of tannery: A waste to wealth approach. Journal of Cleaner Production, 113, 338-344. https://doi.org/10.1016/j.jclepro.2015.11.087

7. Rafikov, A. S., Nabiev, N. D., Karimov, S. Kh., Ibodulloev, B. Sh., & Mirzaev, N. B. (2019). Getting graft cellulose copolymers and acrylic monomers. International Journal of Recent Technology and Engineering, 8(4), 719–723. https://doi.org/10.35940/ijrte.D6816.118419

8. Alongi, J., Carletto, R. A., Bosco, F., Carosio, F., Di Blasio, A., Cuttica, F., Antonucci, V., Giordano, M., & Malucelli, G. (2014). Caseins and hydrophobins as novel green flame retardants for cotton fabrics. Polymer Degradation and Stability, 99, 111-117. https://doi.org/10.1016/j.polymdegradstab.2013.11.016

9. Liu, Y., Wang, Q. Q., Jiang, Z. M., Zhang, C. J., Li, Z. F., Chen, H. Q., & Zhu, P. (2018). Effect of chitosan on the fire retardancy and thermal degradation properties of coated cotton fabrics with sodium phytate and APTES by Layer-by-Layer assembly. Journal of Analytical and Applied Pyrolysis, 135, 289-298. https://doi.org/10.1016/j.jaap.2018.08.024

10. Liu, X., Zhang, Q., Peng, B., Ren, Y., Cheng, B., Ding, C., Su, X., He, J., & Lin, S. (2020). Flame retardant cellulosic fabrics via layer-by-layer self-assembly double coating with egg white protein and phytic acid. Journal of Cleaner Production, 243, 118641. https://doi.org/10.1016/j.jclepro.2019.118641

11. Bacardit Dalmases, A., Borràs Fillat, M. D., Soler Solé, J., Herrero, V., Jorge Sánchez, J., & Ollé Otero, L. (2010). Behavior of leather as a protective heat barrier and fire resistant material. Journal of the American Leather Chemists Association, 105(2), 51–61.

12. Horacek, H., & Grabner, R. (1996). Advantages of flame retardants based on nitrogen compounds. Polymer Degradation and Stability, 54(2–3), 205-215. https://doi.org/10.1016/S0141-3910(96)00045-6

13. Liu, Y., Zhang, A., Cheng, Y., Li, M., Cui, Y., & Li, Z. (2023). Recent advances in biomass phytic acid flame retardants. Polymer Testing, 124, 108100. https://doi.org/10.1016/j.polymertesting.2023.108100т

14. 10. Hassan, M. N., Abdullah, T. S., Mou, M. B., & Towsif, H. R. (2024). Analysis of the flame retardancy effect of boron-containing compound on polyester-cotton blended fabric. Heliyon, 10(13), e34007. https://doi.org/10.1016/j.heliyon.2024.e34007

15. Lu, S.-Y., & Hamerton, I. (2002). Recent developments in the chemistry of halogen-free flame retardant polymers. Progress in Polymer Science, 27(8), 1661–1712. https://doi.org/10.1016/S0079-6700(02)00018-7