REACTIONS OF SODIUM ACRYLATE AND SODIUM METHACRYLATE WITH MONOCHLOROACETIC ACID BENZYL ETHER

Authors

  • Xolmoʻminov Farrux Qo‘chqor ugli Teaching assistant, Department of "Natural Sciences", Tashkent State Transport University
  • Ergasheva Hikoyat Turabovna Teaching assistant, Department of "Natural Sciences", Tashkent State Transport University

DOI:

https://doi.org/10.55640/

Keywords:

Sodium acrylate; sodium methacrylate; monochloroacetic acid benzyl ether; nucleophilic substitution; alkylation reactions; acrylic derivatives; methacrylic derivatives; functional monomers; polymer intermediates.

Abstract

 The reactions of sodium acrylate and sodium methacrylate with monochloroacetic acid benzyl ether were investigated in order to study their nucleophilic substitution behavior and the formation of functionalized acrylic derivatives. The interaction proceeds via the alkylation of the carboxylate anion, leading to the introduction of benzyl ether fragments into the acrylic and methacrylic systems. Reaction conditions, including solvent, temperature, and reaction time, were optimized to improve yield and selectivity. The structures of the obtained products were confirmed using spectroscopic methods. The results demonstrate that both sodium acrylate and sodium methacrylate exhibit comparable reactivity toward monochloroacetic acid benzyl ether, with differences attributed to the steric and electronic effects of the methyl substituent in methacrylate. The synthesized compounds are of interest as intermediates for polymer modification and functional material synthesis.

 

Downloads

Download data is not yet available.

References

Burkart MD et al. Opportunities and challenges for catalysis in carbon dioxide utilization //ACS Catalysis. - 2019. - T. 9. – no. 9. - S. 7937-7956.

2. Doucet H. et al. General synthesis of (Z)-alk-1-en-1-yl esters via ruthenium-catalyzed anti-Markovnikov trans-addition of carboxylic acids to terminal alkynes //The Journal of Organic Chemistry. - 1995. - T. 60. – no. 22. - S. 7247-7255.

3. Hertler WR et al. Group transfer polymerization with polyunsaturated esters and silyl polyenolates //Journal of the American Chemical Society. - 1988. - T. 110. - no. 17. - S. 5841-5853.

4. Liu X., Jia J., Rueping M. Nickel-catalyzed C–O bond-cleaving alkylation of esters: direct replacement of the ester moiety by functionalized alkyl chains //ACS Catalysis. - 2017. - T. 7. – no. 7. - S. 4491-4496.

Downloads

Published

2026-02-07

How to Cite

REACTIONS OF SODIUM ACRYLATE AND SODIUM METHACRYLATE WITH MONOCHLOROACETIC ACID BENZYL ETHER. (2026). Journal of Multidisciplinary Sciences and Innovations, 5(02), 551-553. https://doi.org/10.55640/

Similar Articles

1-10 of 484

You may also start an advanced similarity search for this article.